Yes you would make a female mold using the hood as the male "buck". Then the thin, actual part would be made on the female mold. That gives it a very smooth surface finish even before painting. I would suggest working with air-dry vinyl-ester resin, forget about heat curing for now you don't have a 6 foot square oven anyways.
I buy cloth that is 50-60" wide which would work well for a hood. You'd want some very light random mat fiberglass down first for the surface (sometimes called angel hair), followed by 2-3 layers of the carbon, one layer laid at a 45 degree angle to the others. I'm guessing 15-20 pounds for a hood for an amatuer attempt (sorry not an insult just that it takes experinece to get the weight down). Those seven pound hoods you hear about require pre-preg resin and an autoclave to cure.
Note that the mold would be all fiberglass as it is much cheaper, and needs to be laid much heavier so you don't have distortion.
You need carnuba wax for mold release, fiberglass, carbon, brushes, rollers, a respirator, about 3 gallons of vinyl ester, some polyethylene mixing tubs for the resin, and a lot of balls.
An assistant for the lay-up would be nice as the pieces are large.
Buy a book, there are some good ones on
www.fiberglast.com
Thier prices are stupid-high though, I buy from JR Sweet.